Answer:
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Explanation:
(i) Voltaic cell
A voltaic cell is a device that uses a chemical reaction to produce electrical energy.
(ii) Overall Cell Potential
The standard reduction potentials for the half-reactions are
Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā ā°Ā°/V
Cu²⺠+ 2eā» ā Cu Ā Ā 0.34
Zn²⺠+ 2eā» ā Zn Ā -0.76
The half-reaction with the more positive potential is the reduction half-reaction. It is the reaction that occurs at the cathode.
The half-reaction with the more negative potential is the oxidation half-reaction. It is the Ā reaction that occurs at the anode.
We reverse that half-reaction and subtract the voltages to get the cell reaction.
Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā Ā ā°Ā°/V
Cathode: Ā Cu²⺠+ 2eā» ā Cu Ā Ā Ā Ā Ā Ā Ā 0.34
Anode: Ā Ā Zn ā Zn²⺠+ 2eā» Ā Ā Ā Ā Ā Ā Ā -0.76
Cell: Ā Ā Ā Ā Ā Zn + Ā Cu²⺠ā Zn²⺠+ Cu Ā Ā 1.10
[tex]\mathcal{E}_{\text{cell}}^{\circ} = \mathcal{E}_{\text{cat}}^{\circ} - \mathcal{E}_{\text{an}}^{\circ} = \text{0.34 V} - \text{(-0.76 V)} = \text{0.34 V} + \text{0.76 V} = \textbf{1.10 V}[/tex]
(iii) Diagram
The specific labels will depend on your textbook.
They are often as follows.
a. Electron flow
b. Voltmeter or lightbulb
c. Electron flow
d. Cathode or Cu
e. Cu²āŗ(aq) and NOāā»(aq)
f. Salt bridge
g. Zn²āŗ(aq) and NOāā»(aq)
h. Anode or Zn
The salt bridge enables ions to flow in the internal circuit and to maintain electrical neutrality in the two compartments.
It often consists of a saturated solution of KCl.
As Zn²⺠ions form in the anode compartment, Cl⻠ions move in to provide partners for them.
As Cu²⺠ions are removed from the cathode compartment, K⺠ions move in to replace them.
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